Crystal structure of di-µ-(dimethylsilylene)-bis[tricarbonyl(trimethyl-silyl)ruthenium(III)] and a re-evaluation of the metal–metal interaction in tri-µ-chloro-diruthenium complexes

Autor:	M. M. Crozat, S. F. Watkins
Rok vydání:	1972
Předmět:	Diffraction Crystallography chemistry Silylation Molecule chemistry.chemical_element General Chemistry Crystal structure Tin Diffractometer Monoclinic crystal system Ruthenium
Zdroj:	J. Chem. Soc., Dalton Trans.. :2512-2515
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9720002512
Popis:	The molecular structure of the title compound has been determined by single-crystal X-ray diffraction analysis from diffractometer data. The structure was solved by Patterson and Fourier methods and refined by least squares to R 0·060 for 658 independent reflections. Crystals are monoclinic, space group P21/c, a= 10·64, b= 9·34, c= 14·00, β= 109°, Z= 2. The molecule, which is similar to its tin analogue, contains a Ru–Ru bond of 2·96 A. The relevance of this result to metal–metal bonding in tri-µ-chloro-diruthenium complexes is discussed.
Databáze:	OpenAIRE
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