Zeeman spectroscopy and crystal-field analysis of low symmetry centres in Nd3+ doped Y2SiO5

Autor:	Y Alizadeh, J-P R Wells, M F Reid, A Ferrier, P Goldner
Rok vydání:	2023
Předmět:	General Materials Science Condensed Matter Physics
Zdroj:	Journal of Physics: Condensed Matter. 35:305502
ISSN:	1361-648X 0953-8984
DOI:	10.1088/1361-648x/acceed
Popis:	We report on infrared to visible Zeeman absorption spectroscopy and parameterised crystal-field modelling of Nd3+ centres in Y2SiO5 through the use of experimentally inferred crystal-field energy levels and Zeeman directional electronic g values. We demonstrate that good agreement between the calculated and experimental crystal-field energy levels as well as directional Zeeman g values along all three crystallographic axes can be obtained. Further, we demonstrate that the addition of correlation crystal field effects successfully account for discrepancies that arise between the calculated and experimental values relevant to the 2H 11 / 2 (2) multiplet in a one-electron crystal field model.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c83fbe3e9ef4f2693e3a7c2ba7492e98 https://doi.org/10.1088/1361-648x/acceed Zobrazit plný text záznamu