Polymerization of Dodecylammonium-2-acrylamido-2-methylpropane Sulfonate in Solvents with Different Dielectric Constants and Study of the Resulting Ionic Complexes
| Autor: | Tatjana M. Sukhanova, Ivan M. Zorin, Alexander Yu. Bilibin, Nikolay I. Matuschkin, A. B. Mel’nikov |
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| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Inorganic chemistry Cationic polymerization Solution polymerization Polymer Condensed Matter Physics chemistry.chemical_compound Monomer Sulfonate chemistry Polymerization Polymer chemistry Materials Chemistry Counterion Ionic polymerization |
| Zdroj: | Macromolecular Symposia. :160-168 |
| ISSN: | 1022-1360 |
| DOI: | 10.1002/masy.201100112 |
| Popis: | Counterion polymerization of (DDA-AMPS) is suggested as a new route for preparation of organosoluble polyelectrolyte-surfactant complexes. The polymerization was performed in water and water-dioxane mixed solvent systems. Micellar properties of the monomer were studied. High molecular weight samples of the polymer complex (above 106) were obtained in solvent systems with high and small (0–5%) content of water. The complexes were studied in organic solutions by viscometry, isothermal diffusion, and by AFM on mica and as free films. |
| Databáze: | OpenAIRE |
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