Hydrated electron decay measurements with picosecond pulse radiolysis at elevated temperatures up to 350°C

Autor:	G. Vigneron, F. Gobert, Stanislas Pommeret, J.-P. Larbre, V. De Waele, H. Monard, G. Baldacchino, Jean-Louis Marignier, Sébastien Sorgues, Mehran Mostafavi
Rok vydání:	2006
Předmět:	Range (particle radiation) Chemistry Analytical chemistry General Physics and Astronomy Particle accelerator Electron Solvated electron Laser law.invention Absorbance law Picosecond Radiolysis Physical and Theoretical Chemistry
Zdroj:	Chemical Physics Letters. 424:77-81
ISSN:	0009-2614
Popis:	The present work reports the first pulse-probe absorbance measurements of the hydrated electron at picosecond range and at elevated temperature. The decay of the hydrated electron, from room temperature up to 350 °C, is observed at 790 nm using a laser triggered picosecond electron accelerator. With increasing temperature, the decay of the hydrated electron becomes less and less pronounced. At 350 °C, almost a flat signal from 100 ps to 2.75 ns is observed, suggesting an efficient escape of hydrated electrons from spur reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c82ee54246b9c63dfad3060abeecf5fe https://doi.org/10.1016/j.cplett.2006.04.061 Zobrazit plný text záznamu Full Text from ScienceDirect