Identification of PdPt alloys for preferential C6 olefin hydrogenation over aromatic hydrocarbons through density functional theory and microkinetic modeling
Autor: | Haowen Ma, Jiayi Wang, Xuecheng Zhan, Yuan Xie, Limin Sun, Xiaoli Hu, Haoxiang Xu, Daojian Cheng |
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Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Chemical Communications. 59:6529-6532 |
ISSN: | 1364-548X 1359-7345 |
DOI: | 10.1039/d3cc01856c |
Popis: | Pd3Pt1 is identified with high selectivity (low aromatic depletion), while Pd1Pt1 and Pd1Pt3 are more active for olefin hydrogenation. The PdPt alloys present superior sulfur tolerance compared to Pd. |
Databáze: | OpenAIRE |
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