Two-photon REMPI spectra from and to in O2

Autor:	Stephen Gibson, Richard A. Copeland, J S Morrill, Tom G. Slanger, Eunsook S. Hwang, Marshall L. Ginter, Brenton Lewis
Rok vydání:	2003
Předmět:	Physics symbols.namesake Photon Valence (chemistry) Two-photon excitation microscopy Molecular vibration Rydberg formula symbols Physical and Theoretical Chemistry Atomic physics Spectroscopy Atomic and Molecular Physics and Optics Spectral line
Zdroj:	Journal of Molecular Spectroscopy. 219:200-216
ISSN:	0022-2852
DOI:	10.1016/s0022-2852(03)00074-2
Popis:	Well-calibrated, resonance-enhanced multiphoton-ionization (REMPI) spectra of eight bands of d 1 Π g ←a 1 Δ g and four bands of d 1 Π g ←b 1 Σ g + in O2 have been recorded and analyzed. These data provide detailed characterizations of the complex rotational structures in the five lowest vibrational levels (v=0–4) of the d 1 Π g state. The observed complexities in the rovibronic structure of d 1 Π g are the result of strong perturbations between the d 1 Π g Rydberg and the II 1 Π g valence states. Weaker perturbations resulting from interactions between d and the II 1 Δ g valence state also are observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c8240e31b9b983cd2b3581a824b7a5c9 https://doi.org/10.1016/s0022-2852(03)00074-2 Zobrazit plný text záznamu Full Text from ScienceDirect