Determination of multiple electron affinities of carbon disulfide using electron-capture detection

Autor:	Rajan George, E.S.D Chen, E. C. M. Chen, Sandra Carr, Wayne E. Wentworth
Rok vydání:	1998
Předmět:	chemistry.chemical_classification Carbon disulfide Electron capture Organic Chemistry Analytical chemistry General Medicine Biochemistry Analytical Chemistry Ion chemistry.chemical_compound Electron capture detector chemistry Electron affinity Cluster (physics) MINDO Inorganic compound
Zdroj:	Journal of Chromatography A. 811:250-255
ISSN:	0021-9673
DOI:	10.1016/s0021-9673(98)00199-x
Popis:	The electron affinities (EAs) for carbon disulfide in the literature cluster around two values, 0.895±0.02 eV and 0.55±0.06 eV. Two negative ion states are observed in the temperature dependence of the electron-capture detector. The EAs obtained from these data are 0.61±0.04 eV for the linear anion and 0.873±0.025 eV for the bent anion. The theoretical semi-empirical MINDO/3 EAs are 0.582 eV and 0.891 eV. These support the literature values for the two states and establish the most appropriate values.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c80ff6438d905c460e0dce3f09af927a https://doi.org/10.1016/s0021-9673(98)00199-x Zobrazit plný text záznamu Full Text from ScienceDirect