The composition of catalytically active centres of oxides in the double bond shift of olefins

Autor:	G. Resofszki, G. Gáti
Rok vydání:	1989
Předmět:	chemistry.chemical_classification Double bond General Engineering Ion pairs Photochemistry Catalysis Metal chemistry Deuterium visual_art Intramolecular force Polymer chemistry visual_art.visual_art_medium Composition (visual arts) Isomerization
Zdroj:	Journal of Molecular Catalysis. 51:295-302
ISSN:	0304-5102
DOI:	10.1016/0304-5102(89)80008-2
Popis:	Double bond isomerization of 1-hexene, 2-methyl-1-pentene and 3-methyl-1-pentene has been studied on CaO, La 2 O 3 , ZrO 2 , Al 2 O 3 and MoO 3 , selected to represent a broad scale of acid-base properties of catalysts. Changes in relative reactivities after partial poisoning by CO 2 and NH 3 , and the results of tracer studies with deuterated oxides and olefins provided direct experimental evidence that active centre ensembles are metal ionoxide ion pairs; surface OHs are not involved, and H transfer is intramolecular on all five oxides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c80cb2e29c9fd675b2cb4a2743918fbe https://doi.org/10.1016/0304-5102(89)80008-2 Zobrazit plný text záznamu