Unusual lithium coordinated platinum and rhodium hydride dimers

Autor: Stephen S. Oster, William W. Brennessel, William D. Jones, Tülay A. Ateşin, Matthew R. Grochowski, Brett D. Swartz
Rok vydání: 2010
Předmět:
Zdroj: Inorganica Chimica Acta. 363:517-522
ISSN: 0020-1693
DOI: 10.1016/j.ica.2009.05.013
Popis: Two unusual lithium coordinated binuclear platinum- and rhodium-hydride complexes [M(dippe)(H)]2·LiHBEt3 were synthesized and characterized by NMR spectroscopy and X-ray crystallography. Not only does the lithium ion interact with the metal hydrides, but also with the B–H bond of the borohydride.
Databáze: OpenAIRE