Size-Selective Silver-Induced Evolution of Mn3O4−Ag Nanocomposites for Effective Ethanol Sensing

Autor: Sujit Kumar Ghosh, Hasimur Rahaman, Susmita Kundu
Rok vydání: 2017
Předmět:
Zdroj: ChemistrySelect. 2:6991-6999
ISSN: 2365-6549
DOI: 10.1002/slct.201700321
Popis: Trimanganese tetraoxide (Mn3O4)-silver (Ag) nanocomposites have been synthesized by seed-mediated growth of manganese oxide by alkaline hydrolysis of manganese precursor on preformed silver nanoparticles at water/n-heptane interface. The morphology of the nanocomposites has been varied by individual addition of five size-selective silver nanoparticles for the evolution of the manganese components. Varieties of spectroscopic and microscopic techniques have been used to characterize these materials. Now, the efficacy of these as-synthesized nanocomposites has been demonstrated towards the sensing of various hazardous volatile organic compounds, exhibiting high sensitivity to ethanol compared to other components. Moreover, the structure-function relationship of the Mn3O4-Ag nanocomposites upon variation of the size of silver particles towards the sensory activity of ethanol has been elucidated.
Databáze: OpenAIRE