π-halogen interaction on the crystalline packing of 1,3,5-tris(4-bromophenyl)-1,3,5-triazine-2,4,6-trione·[solvate]

Autor:	Alexander Trujillo, Carlos A. Escobar, Vania Artigas, Mitchell Bacho
Rok vydání:	2022
Předmět:	Chloroform Recrystallization (geology) Chemistry Hydrogen bond Organic Chemistry Crystal structure Analytical Chemistry Inorganic Chemistry Crystal Solvent Crystallography chemistry.chemical_compound 1 3 5-Triazine Molecule Spectroscopy
Zdroj:	Journal of Molecular Structure. 1247:131307
ISSN:	0022-2860
Popis:	This paper discloses the synthesis of 1,3,5-Tris(4-bromophenyl)-1,3,5-triazin-2,4,6-trione·CHCl3, (Cy·CHCl3). The title compound was purified by recrystallization in chloroform. Structural and crystalline analysis reveals that Cy·CHCl3 crystallizes in the trigonal space group R3c. The high symmetry is due to the finding in the crystal of the existence of a π-halogen intermolecular interaction between the title compound and one chloroform molecule as lattice solvent, forming a honeycomb-shape pattern when the isocyanurate core centroids are joined in the packing diagram. Also, crystal structure of Cy·CHCl3 reveals that cell packing is stabilized by hydrogen bond interactions. All interactions were verifying through Hirshfeld surface analyses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c7ea841cc762c8f91e74fda8ab77990c https://doi.org/10.1016/j.molstruc.2021.131307 Zobrazit plný text záznamu Full Text from ScienceDirect