Coordination chemistry of copper-(i) and -(ii) with 2-pyridylmethyl substituted triazacyclohexanes

Autor:	Randolf D. Köhn, Mary F. Mahon, Zhida Pan, Gabriele Kociok-Köhn
Rok vydání:	2003
Předmět:	Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound chemistry Cubane Yield (chemistry) chemistry.chemical_element Organic chemistry Reactivity (chemistry) Medicinal chemistry Copper Single crystal Coordination complex
Zdroj:	Dalton Trans.. :2269-2275
ISSN:	1477-9234 1477-9226
Popis:	The syntheses of several novel copper-(I) and -(II) compounds containing triazacyclohexanes with one or three 2-pyridylmethyl substituents are described. The molecular structures of (2-PyMe)3TACCuCl23, [(2-PyMe)Et2TACCuCl2]24 and [(2-PyMe)3TACCuI](BF4) 5 have been determined by single crystal X-ray diffraction. The reactivity of 5 and [(2-PyMe)Et2TACCu](BF4) 7 towards dioxygen was investigated and a very stable oxidation product with a Cu4(OH)4 cubane core could be obtained in high yield simply by exposing 7 to the atmosphere.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c7d6b19012404da12712fc93129fe829 https://doi.org/10.1039/b302037a Zobrazit plný text záznamu