ELECTROCHEMICAL CARBON-SKELETON REARRANGEMENT AS CATALYZED BY HYDROPHOBIC VITAMIN B12IN NONAQUEOUS MEDIA

Autor:	Yukito Murakami, Yoshio Hisaeda, Yoshihisa Matsuda, Takako Tashiro
Rok vydání:	1985
Předmět:	Electrolysis Chemistry Halogenation General Chemistry Electrochemistry Electrocatalyst Catalysis law.invention Acetic acid chemistry.chemical_compound law Enzyme model Polymer chemistry Organic chemistry Aliphatic compound
Zdroj:	Chemistry Letters. 14:1813-1816
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1985.1813
Popis:	The controlled-potential electrolysis of 2,2-bis(ethoxycarbonyl)-1-bromopropane at −1.50 V vs. SCE as catalyzed by a hydrophobic vitamin B12 in DMF proceeded to give 1,2-bis(ethoxycarbonyl)propane as a major product in the presence of acetic acid under argon atmosphere in the dark.
Databáze:	OpenAIRE
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