Some reactions of trifluoromethanesulfonic anhydride with various metal substrates

Autor: Debyani G. Niyogi, Sandeep Singh, R. D. Verma, Sonu Gill
Rok vydání: 1990
Předmět:
Zdroj: Journal of Fluorine Chemistry. 48:421-428
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)80226-2
Popis: Reactions of trifluoromethanesulfonic anhydride with various metal substrates were carried out in an attempt to prepare metal trifluoro-methanesulfonates. New trifluoromethanesulfonates, viz; NaBi(SO 3 CF 3 ) 4 , Na 2 Te(SO 3 CF 3 ) 6 , K 2 SeO 2 (SO 3 CF 3 ) 4 and Ti(OCH 3 ) 2 (SO 3 CF 3 ) 2 have been prepared by reacting NaBi(CF 3 COO) 4 , Na 2 Te(CF 3 COO) 6 or Na 2 TeO 3 , K 2 SeO 4 and Ti(OCH 3 ) 4 respectively, with (CF 3 SO 2 ) 2 O. These compounds have been characterized by elemental analyses and infrared and 19 F NMR spectra.
Databáze: OpenAIRE