Synthesis, Structure, Dynamics, and Enantioface-Selective η3-Benzyl Coordination in the Chiral Rhodium Complexes Rh(diphos*)(η3-CH2Ph)

Autor:	Curtis E. Moore, David S. Glueck, Arnold L. Rheingold, Russell P. Hughes, Sarah T. Chachula, Perry M. Scheetz, Milan Gembicky
Rok vydání:	2020
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Organic Chemistry Polymer chemistry Enantioselective synthesis chemistry.chemical_element Physical and Theoretical Chemistry Phosphine Rhodium
Zdroj:	Organometallics. 39:3802-3816
ISSN:	1520-6041 0276-7333
DOI:	10.1021/acs.organomet.0c00516
Popis:	The rhodium benzyl complexes Rh(diphos*)(η3-CH2Ph) (1–14, diphos* = chiral bis(phosphine)), potential precursors for asymmetric catalysis, were prepared either by treatment of Rh(COD)(η3-CH2Ph) (15...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c786b2e81664cbf00ecbee375a199213 https://doi.org/10.1021/acs.organomet.0c00516 Zobrazit plný text záznamu