Nickel/Zinc Iodide Co-catalytic Asymmetric [2+2] Cycloaddition Reactions of Azabenzonorbornadienes with Terminal Alkynes

Autor:	Xin Xu, Hongyu Qin, Sun Weiqing, Jingchao Chen, Zhenxiu He, Baomin Fan
Rok vydání:	2017
Předmět:	chemistry.chemical_classification 010405 organic chemistry Iodide chemistry.chemical_element Alkyne General Chemistry Zinc 010402 general chemistry 01 natural sciences Combinatorial chemistry Cycloaddition 0104 chemical sciences Catalysis Nickel chemistry Organic chemistry Nickel zinc
Zdroj:	Advanced Synthesis & Catalysis. 360:427-431
ISSN:	1615-4150
DOI:	10.1002/adsc.201701133
Popis:	The asymmetric [2+2] cycloaddition reactions of alkenes with alkynes are interesting as it has provided a powerful method for the construction of fused and strained cyclobutenes with multiple chiral centers. In this paper, we report the establishment of a dual catalysts system comprising nickel and zinc, which allowed the asymmetric [2+2] cycloaddition reactions of azabenzonorbornadienes with terminal alkynes in good yields and excellent enantioselectivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c75a36c54303d250e6562329925a93c0 https://doi.org/10.1002/adsc.201701133 Zobrazit plný text záznamu