Transition metal catalyzed ring-opening polymerization of silicon-bridged [1]ferrocenophanes at ambient temperature

Autor:	Ron Rulkens, Yizeng Ni, John K. Pudelski, Ian Manners
Rok vydání:	1995
Předmět:	Polymers and Plastics Silicon Dimer Organic Chemistry chemistry.chemical_element Photochemistry Ring-opening polymerization Catalysis chemistry.chemical_compound chemistry Transition metal Polymerization Cyclooctene Polymer chemistry Materials Chemistry
Zdroj:	Macromolecular Rapid Communications. 16:637-641
ISSN:	1521-3927 1022-1336
Popis:	A new route to poly(ferrocenylsilanes) under mild conditions via the ring-opening polymerization of silicon-bridged [1]ferrocenophanes is presented. Catalytic amounts of the transition metal complexes [Rh(cyclooctene)2(μ-Cl)]2, Pd(1,5-cyclooctadiene)Cl2, PdCl2 and PtCl2 in C6D6 at room temperature afforded high molecular weight poly(ferrocenylsilanes) (2). In some cases a symmetrical dimer (3) was obtained as a byproduct.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c747067496de967033a7d9459b4cf5ae https://doi.org/10.1002/marc.1995.030160901 Zobrazit plný text záznamu Plný text