Molecular Photonics of 2,4-Dibenzylidenecyclobutanone and Its Derivatives

Autor:	Alexander K. Chibisov, Sergey P. Gromov, G. V. Zakharova, V. N. Gutrov, R. O. Starostin, M. V. Fomina, V. N. Nuriev
Rok vydání:	2020
Předmět:	010302 applied physics 010304 chemical physics Chemistry Pulse (signal processing) business.industry Photochemistry Laser 01 natural sciences Fluorescence law.invention Absorption band law 0103 physical sciences Physical and Theoretical Chemistry Triplet state Photonics Luminescence business
Zdroj:	High Energy Chemistry. 54:303-307
ISSN:	1608-3148 0018-1439
Popis:	Spectral, luminescent, and time-resolved properties of 2,4-dibenzylidenecyclobutanone and its diethylamino, methylthio, methoxy, and dimethoxy derivatives have been studied. The electron-donating substituents shift bathochromically the absorption band maximum by 45–140 nm relative to unsubstituted dienones and the fluorescence maximum by 50–125 nm relative to the methoxy derivative. Upon the laser pulse, dienones convert to the triplet state with a lifetime of 0.15–3.5 μs and a stable photoproduct is formed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c73be5dc68e2d4ad9819fd39b587232a https://doi.org/10.1134/s0018143920050069 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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