Ortho-metallation of η-pyrrolylmetal complexes with triosmium clusters

Autor:	Alejandro J. Arce, Carola Acuña, Antony J. Deeming
Rok vydání:	1988
Předmět:	Nitrile Stereochemistry Organic Chemistry Metallacycle Ring (chemistry) Biochemistry Oxidative addition Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Sandwich compound Materials Chemistry Cluster (physics) Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 356:C47-C49
ISSN:	0022-328X
Popis:	The cluster [O3(CO)10(MeCN)2] reacts with (η-cyclopentadienyl)(η-pyrrolyl)iron [azaferrocene, Fe(C5H5)(C4H4N) under mild conditions to give the oxidative addition product [Os3H{(C4H3N)Fe(C5H5)}(CO)10]. The group (C4H3N)Fe(C5H5) acts as a three-electron donor through the ortho-metallated pyrrolyl ring. An analogous compounds, [Os3H{(C4H3N)Mn(CO)3}(CO)10], is obtained by the reaction of [Os3(CO)10(MeCN)2] with [Mn(η-pyrrolyl)(CO)3].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c724aa6c772d771c82e5e1106d4c9364 https://doi.org/10.1016/0022-328x(88)83098-5 Zobrazit plný text záznamu