Mechanisms of reactions of organoaluminium compounds with alkenes and alkynes catalyzed by Zr complexes

Autor:	Lyudmila Parfenova, Lilya Dzhemileva, Leonard M. Khalilov, Usein Dzhemilev
Rok vydání:	2012
Předmět:	Steric effects Metal Reaction conditions Zirconium Chemistry visual_art visual_art.visual_art_medium chemistry.chemical_element Organic chemistry Stereoselectivity General Chemistry Catalysis
Zdroj:	Russian Chemical Reviews. 81:524-548
ISSN:	1468-4837 0036-021X
DOI:	10.1070/rc2012v081n06abeh004225
Popis:	The results of studies dealing with mechanisms of hydro-, carbo- and cycloalumination of alkenes and alkynes catalyzed by zirconium complexes are generalized and systematized for the first time. Data about the structures of intermediates responsible for the formation of the target compounds are presented and the available data on the effect of the structure of organoaluminium compounds and the electronic and steric factors determining the catalytic activity of metal complexes in these reactions are considered in detail. Much attention is paid to studies of the influence of reaction conditions on the chemo-, regio- and stereoselectivity of the Zr-containing complex catalysts. The bibliography includes 217 references.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c71756bbbf7f44e8ec99fa0097b15048 https://doi.org/10.1070/rc2012v081n06abeh004225 Zobrazit plný text záznamu