Comprehensive Experimental and Computational Study of η6-Arene Ruthenium(II) and Osmium(II) Complexes Supported by Sulfur Analogues of the β-Diketiminate Ligand
| Autor: | Conor Robinson, Crystal O’Connor, Andrew D. Phillips, Helge Müller-Bunz, Darren C. Lawlor |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Chemistry Ligand Organic Chemistry Cationic polymerization chemistry.chemical_element 010402 general chemistry 01 natural sciences Sulfur 0104 chemical sciences Ruthenium Inorganic Chemistry Metal Reagent visual_art Polymer chemistry visual_art.visual_art_medium Osmium Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Organometallics. 37:1860-1875 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/acs.organomet.8b00111 |
| Popis: | In comparison to β-diketiminates, a highly exploited class of N,N-chelating ligands, the corresponding β-thioketoiminates, monothio-substituted analogues, have received only minor attention. β-Thioketoiminates are straightforwardly prepared through treatment of an appropriate β-ketoiminate with Lawesson’s reagent. Employing standard synthetic techniques for η6-arene Ru(II) and Os(II) β-diketiminate complexes, an analogous series of chlorido-metal complexes supported by different sized N-aryl substituted β-thioketoiminate ligands is reported. However, metal ligation of a β-thioketoiminate bearing an electron-withdrawing CF3 group was not possible. The metal–chlorine bond in these complexes is readily activated by various sodium or silver salts of weakly coordinating anions, affording coordinately unsaturated cationic formally 16-electron species. All η6-C6H6 metal β-thioketoiminate complexes were characterized by NMR and in the solid state using single crystal X-ray diffraction techniques. Structural studi... |
| Databáze: | OpenAIRE |
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