Elastomer-Modified Vinyl Esters as Structural Adhesives
| Autor: | C. D. Guiley, A. R. Siebert, D. R. Egan, R. S. Drake, P. J. Pearce |
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| Rok vydání: | 1995 |
| Předmět: |
Materials science
technology industry and agriculture Vinyl ester macromolecular substances Surfaces and Interfaces General Chemistry Elastomer Vinyl polymer Surfaces Coatings and Films Polyester chemistry.chemical_compound Natural rubber Methacrylic acid chemistry Mechanics of Materials visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Organic chemistry Nitrile rubber Curing (chemistry) |
| Zdroj: | The Journal of Adhesion. 49:245-259 |
| ISSN: | 1545-5823 0021-8464 |
| DOI: | 10.1080/00218469508014358 |
| Popis: | Vinyl esters (epoxy-methacrylates) are preeminent chemical-and corrosion-resistant materials. Based primarily on addition-esterified cpoxy resins with methacrylic acid and diluted with styrene monomer, several products are available based on dicpoxide structure, molecular weight, modifier type (nitrile rubber, urethane. elycol, e.g.) and blends with styrenated polyester resins. A new dass of vinyl ester urethanes has also become commercially available. Elastomer modification of both types has shown that the fracture energy of epoxv vinyl esters can be enhanced to have a four-fold improvement Despite this, the elastomer-modified vinyl esters have not found use as a basis for free-radical curing structural adhesives. Addition of an epoxy-terminated rubber (ETBN) or a methacrylated-vinyl terminated rubber (VTBNX) to previously elastomermodified vinyl ester resin significantly improves overlap shear, T-peel, and bulk fracture propertics. This suggests potential application in structural adhesive deve... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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