Optimization of hydrolytic decomposition of 4,4-dimethyl-1,3-dioxane to 3-methylbutane-1,3-diol under isobutylene pressures by statistical planning of the experiment☆

Autor:	L. Kh. Freidlin, V. Z. Sharf, V. I. Kheifets, T.D. Basnina, G. K. Oparina, M. K. Bychkova
Rok vydání:	1966
Předmět:	Isobutylene integumentary system Diol General Engineering Reaction zone Formaldehyde Alcohol Decomposition chemistry.chemical_compound Hydrolysis chemistry Yield (chemistry) Organic chemistry hormones hormone substitutes and hormone antagonists
Zdroj:	Petroleum Chemistry U.S.S.R.. 6:136-141
ISSN:	0031-6458
DOI:	10.1016/0031-6458(66)90077-3
Popis:	To displace the equilibrium in the direction of diol formation, the formaldehyde separated in the reaction should be combined. Farberov and Shemyakin [3] hydrolysed dioxane in the presence of methyl alcohol which with formaldehyde gave methylal distilled from the reaction zone. Diol yield was under 50% calculated on the dioxane taken. In this s tudy hydrolysis of 4,4-dimethyl-l,3-dioxane was carried out under pressure of isobutylene reacting with formaldehyde and forming dio
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c6bd24493f6e51ee5667bd0ac20c524d https://doi.org/10.1016/0031-6458(66)90077-3 Zobrazit plný text záznamu