Preparation of New Perfluoroalkylated Carbamate Group-containing Glycoside-based Nonionic Surfactants

Autor: S. Y. Dieng, H. Trabelsi, M. Nasreddine, S. Szönyi
Rok vydání: 2007
Předmět:
Zdroj: Tenside Surfactants Detergents. 44:116-120
ISSN: 2195-8564
0932-3414
Popis: The present work describes the synthesis of new perfluoroalkylated carbamate group-containing glycoside-based nonionic surfactants usable as co-surfactants for stabilizing injectable oxygen-carriers PFC emulsions and as potential antithrombotic agents. The key steps of the synthetic route converting F-alkyl oxoesters into new F-alkyl glycosides are: formolysis, conversion to the respective acid chloride, isocyanate formation and glycosidation. The perfluoroalkyl group is connected through a carbamate function to 6-position of the sugar ring, and the glycosidation is performed from unprotected sugar.
Databáze: OpenAIRE