Clean Ar-Me conversion to Ar-aldehyde with the aid of carefully designed metallocor role photocatalysts

Autor:	Zeev Gross, Shachar Fite, David G. Churchill, Qiu-Cheng Chen, Sudhakar Kolanu, Woohyun Lee, Xuan Zhan
Rok vydání:	2020
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Transition metal Singlet oxygen Yield (chemistry) Photooxygenation Substrate (chemistry) Physical and Theoretical Chemistry Photochemistry Mesitylene Aldehyde Toluene
Zdroj:	Photochemical & Photobiological Sciences. 19:996-1000
ISSN:	1474-9092 1474-905X
Popis:	Toluene, p-xylene and mesitylene were cleanly converted to their corresponding monoaldehydes via mild photooxygenation utilizing transition metal and main group β-CF3-substituted corroles. Aldehyde yield increased as more electron-donating CH3 groups are present on the substrate. 4-P was most efficient (TON ∼ 1072, mesitylene) via the singlet oxygen vis the superoxide mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c68d7fa484cf394c2c2382931e2ceb71 https://doi.org/10.1039/d0pp00218f Zobrazit plný text záznamu Full text from SpringerLink