Synthesis and optical properties of new highly NIR reflective inorganic pigments RE6Mo2O15 (RE = Tb, Dy, Ho, Er)
| Autor: | Gerda Fuhrmann, Hubert Huppertz, Daniel Schildhammer, Herwig Schottenberger, Lucas L. Petschnig |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Diffuse reflectance infrared fourier transform business.industry Process Chemistry and Technology General Chemical Engineering Analytical chemistry Color analysis chemistry.chemical_element 02 engineering and technology Orange (colour) 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence 0104 chemical sciences Pigment chemistry Molybdenum visual_art visual_art.visual_art_medium Inorganic pigments Optoelectronics 0210 nano-technology business Hue |
| Zdroj: | Dyes and Pigments. 140:22-28 |
| ISSN: | 0143-7208 |
| DOI: | 10.1016/j.dyepig.2017.01.021 |
| Popis: | Novel near-infrared (NIR) reflecting pigments with colors ranging from yellow to orange to dark brown based on the rare earth molybdenum oxides RE6Mo2O15 (RE = Tb, Dy, Ho, Er) are described. The compounds were prepared by solid state reactions and characterized by XRD analysis and UV–Vis–NIR diffuse reflectance spectroscopy. The compounds RE6Mo2O15 (RE = Tb-Er) crystallize in a trigonal crystal structure with the cell parameters a = 737.6(2)–745.7(2) pm and c = 932.3(1)–946.4(1) pm. For the pigments Er6Mo2O15 and Ho6Mo2O15, optical and detailed color analysis revealed illuminant-dependent, color changing behavior (orange/yellow). Different light emitting sources such as classical bulb, LED, fluorescence lamp, and solar light were used for the characterization of these pigments. A brilliant yellow color hue was obtained for Dy6Mo2O15, whereas Tb6Mo2O15 exhibited a dark brown color. High NIR solar reflectance of 51.1%–98.1% were obtained for Tb6Mo2O15 and Ho6Mo2O15, respectively (recorded in the range between 700 and 2500 nm by using PTFE as reference). |
| Databáze: | OpenAIRE |
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