Autor:	Max Malacria, Louis Fensterbank, Priscille Devin
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Cyclopentanol Chemistry Intramolecular force Radical Cyclohexanol Organic chemistry General Medicine Aldehyde
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199819044
Popis:	The reaction of aldehydes 1 and 10 with Bu 3 SnH has been studied. In thermal conditions, after an initial chemoselective 6- exo-trig or 5- exo-trig cyclization to the aldehyde, a β-scission reaction takes place, providing rearrangement products. At low temperature, using the Et 3 /O 2 procedure, satisfactory yields of cyclohexanol 2 and cyclopentanol 11 are obtained.
Databáze:	OpenAIRE
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