Electrical Conductivity of GdCl3-Gd2O3 Molten System

Autor:	Elena V. Nikolaeva, Irina D. Zakiryanova, Andrey L. Bovet
Rok vydání:	2022
Předmět:	Renewable Energy Sustainability and the Environment Materials Chemistry Electrochemistry Condensed Matter Physics Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Journal of The Electrochemical Society. 169:036511
ISSN:	1945-7111 0013-4651
DOI:	10.1149/1945-7111/ac5b37
Popis:	The electrical conductivity of GdCl3 chloride melts with the gadolinium oxide (Gd2O3) additions ranging from 0 to 5 mol % was measured depending on both the temperature and concentration of Gd2O3. The obtained temperature dependencies can be approximated by Arrhenius-type equation. The calculated effective activation energy values of electrical conductivity increase with the increasing concentration of Gd2O3 above 2.5 mol %. A decrease in the electrical conductivity of the chloride melts when adding the gadolinium oxide according to the Raman spectra data can be explained by the presence of [OGd3Cln] oxychloride associates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c6559ae23dd7f3df7cc078ed435238a0 https://doi.org/10.1149/1945-7111/ac5b37 Zobrazit plný text záznamu