Manipulating the molecular structure of PEDOT chains through controlling the viscosity of PEDOT:PSS solutions to improve the photovoltaic performance of CH3NH3PbI3 solar cells
| Autor: | Hsin Ming Cheng, Chun Guey Wu, Zong Liang Tseng, Wei Nien Chen, Chin-Ti Chen, Sheng Hsiung Chang, Kuo Yuan Chiu, Wen Ti Wu, Lung-Chien Chen, Shih Chieh Yeh, Sheng Hui Chen, Cheng Chiang Chen |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment business.industry Energy conversion efficiency Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Surface energy 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Polystyrene sulfonate Contact angle Crystallinity chemistry.chemical_compound PEDOT:PSS chemistry Chemical engineering Photovoltaics Thin film 0210 nano-technology business |
| Zdroj: | Solar Energy Materials and Solar Cells. 161:7-13 |
| ISSN: | 0927-0248 |
| DOI: | 10.1016/j.solmat.2016.11.020 |
| Popis: | A series of alcohols (methanol, ethanol and isopropyl alcohol) were added to poly(3,4-ethylenedioxythiophene): (polystyrene sulfonate) (PEDOT: PSS) aqueous solutions in order to manipulate the molecular structure of the PEDOT chains in PEDOT: PSS hole transporting materials (HTMs) and thus to improve the power conversion efficiency of CH3NH3PbI3 based solar cells. The structural and electronic characteristics of the resultant PEDOT: PSS HTMs were analyzed using atomic-force microscopy, contact angle measurement, Raman scattering spectrometry and photoelectron spectrometry. The properties of the PEDOT: PSS thin films could be controlled by tuning the viscosity of the PEDOT: PSS solutions. High viscosity PEDOT: PSS solutions resulted in linear structured PEDOT chains, which increased the work function of the PEDOT: PSS HTMs thereby improving the open-circuit voltage of the CH3NH3PbI3 solar cells. The surface roughness and surface free energy of the PEDOT: PSS HTMs influence the structural properties of CH3NH3PbI3 thin films, which determines the exciton dissociation at the CH3NH3PbI3/PEDOT: PSS interface (short-circuit current density) and the carrier recombination at the CH3NH3PbI3/[6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) interface (fill factor). In addition, it is predicted that the power conversion efficiency can be further improved by increasing the crystallinity of the CH3NH3PbI3 thin film. |
| Databáze: | OpenAIRE |
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