N-Heterocyclic carbenes: application of ruthenium–alkylidene complexes in ring-opening metathesis polymerization
| Autor: | Thomas Weskamp, Florian J. Kohl, Oskar Nuyken, Wolfgang A. Herrmann, Wolfgang C. Schattenmann, Ulrich Frenzel |
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| Rok vydání: | 1999 |
| Předmět: |
Chemistry
Transition metal carbene complex Organic Chemistry chemistry.chemical_element Homogeneous catalysis ROMP Biochemistry Ruthenium Inorganic Chemistry chemistry.chemical_compound Polymerization Polymer chemistry Materials Chemistry Ring-opening metathesis polymerisation Organic chemistry Physical and Theoretical Chemistry Norbornene Acyclic diene metathesis |
| Zdroj: | Journal of Organometallic Chemistry. 586:263-265 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(99)00275-2 |
| Popis: | Novel ruthenium–alkylidene catalysts bearing N-heterocyclic carbenes were applied in ring-opening metathesic polymerization (ROMP) reactions of various norbornene derivatives. High tolerance towards polar functional groups as well as high catalytic activity is demonstrated. The combination of N-heterocyclic carbenes and coordinatively labile ligands (phosphanes or chloro-bridged transition metals) on the ruthenium center proves not only successful regarding catalytic performance but also promising with respect to polymer properties. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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