Photo-epoxidation of (α, β)-pinene with molecular O2 catalyzed by a dioxo-molybdenum (VI)-based Metal–Organic Framework

Autor:	Henry Martínez Q., Fernando Martínez O, Pascal Van Der Voort, Nelson J. Castellanos, Karen Leus
Rok vydání:	2021
Předmět:	chemistry.chemical_compound chemistry Molybdenum Polymer chemistry Oxide Photocatalysis chemistry.chemical_element Infrared spectroscopy Metal-organic framework Reactivity (chemistry) General Chemistry Gallium Catalysis
Zdroj:	Research on Chemical Intermediates. 47:4227-4244
ISSN:	1568-5675 0922-6168
DOI:	10.1007/s11164-021-04518-3
Popis:	A gallium-based metal–organic framework, post-modified with MoO2Cl2, was examined as a catalyst for the room temperature liquid-phase photooxidation of α‐ and β-pinene in the presence of molecular oxygen as the oxidant. For both substrates, (α, β)-pinene oxide was formed as the sole product due to the oxygen atom transfer process. Peroxo-molybdenum species was identified in the reoxidation process using infrared spectroscopy. Moreover, a comparison of the structure of the catalyst before and after catalysis by means of X-ray powder diffraction (XRPD), infrared spectroscopy (IR) and N2 adsorption–desorption measurements demonstrated the high recyclability and potential of this catalyst in the photocatalytic epoxidation process of terpenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c62164f7a716b3d0a5e5a2e20d4b78ff https://doi.org/10.1007/s11164-021-04518-3 Zobrazit plný text záznamu Plný text ve formátu PDF