A Reusable Palladium(II)/Cationic 2,2′‐Bipyridyl Catalytic System for Hydroxycarbonylation of Aryl Iodides in Water

Autor:	Sheng‐Wen Tsai, Fu-Yu Tsai, Shao-Hsien Huang, Han‐Sheng Lee
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Aqueous solution Chemistry Aryl Polymer chemistry Cationic polymerization Organic chemistry chemistry.chemical_element Precious metal General Chemistry Catalysis Palladium
Zdroj:	Journal of the Chinese Chemical Society. 60:769-772
ISSN:	2192-6549 0009-4536
Popis:	A water-soluble palladium(II)/cationic 2,2′-bipyridyl system was utilized to catalyze hydroxycarbonylation of aryl iodides in the presence of a pressurized CO atmosphere under a basic aqueous solution at 100 °C. The residual aqueous solution could be reused in several times with only a slight decrease in catalytic activity. Thus, it reduced wastage of the precious metal in the reaction. A variety of aromatic carboxylic acids could still be obtained in high yields with the catalytic amount to 0.01 mol%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c61cfc3abd5056e482c2b8c2b7ee6e62 https://doi.org/10.1002/jccs.201200595 Zobrazit plný text záznamu Plný text ve formátu PDF