Coordination compounds of DyIII and NdIII with malonic and succinic acid bispicolylamidrazones
Autor: | V. F. Shul´gin, Alexey N. Gusev, N. N. Efimov, Vadim V. Minin, Igor L. Eremenko, G. G. Aleksandrov |
---|---|
Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 64:1891-1895 |
ISSN: | 1573-9171 1066-5285 |
DOI: | 10.1007/s11172-015-1089-x |
Popis: | Dysprosium(iii) and neodymium(iii) complexes with aliphatic dicarboxylic acid bispicolyl-amidrazones were synthesized and studied. X-ray diffraction data showed that the compounds under study have a binuclear structure, in which the coordination polyhedra are bound by two aliphatic bridges. When excited with UV radiation, neodymium complexes exhibit weak ionic photoluminescence, while no luminescent activity was shown by dysprosium complexes. The temperature dependence of magnetic susceptibility of dysprosium complexes was studied. |
Databáze: | OpenAIRE |
Externí odkaz: |