ChemInform Abstract: Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

Autor:	Ji Yang, Zheng Huang, Ziqing Zuo
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Hydrosilylation Markovnikov's rule Alkyne chemistry.chemical_element Regioselectivity General Medicine Oxazoline Medicinal chemistry chemistry.chemical_compound Hydroboration chemistry Vinylsilane Cobalt
Zdroj:	ChemInform. 47
ISSN:	0931-7597
Popis:	A pyridinebis(oxazoline) cobalt complex is a very efficient precatalyst for the hydrosilylation of terminal alkynes with Ph2 SiH2 , providing α-vinylsilanes with high (Markovnikov) regioselectivity and broad functional-group tolerance. The vinylsilane products can be further converted into geminal borosilanes through Markovnikov hydroboration with pinacolborane and a bis(imino)pyridine cobalt catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c5da31045ddc48d7505d3b9201274487 https://doi.org/10.1002/chin.201652369 Zobrazit plný text záznamu Plný text