Reactive scattering of B/sup +/(/sup 1/S/sub g/) by molecular deuterium

Autor:	N.A. Sondergaard, I. Sauers, J.J. Kaufman, W.S. Koski
Rok vydání:	1979
Předmět:	Deuterium Isotope Scattering Chemistry TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY Excited state Analytical chemistry Ionic bonding Atomic physics Spectral line Charged particle Ion
DOI:	10.2172/7026576
Popis:	The angular and energy distribution of the ionic products from the reaction of B/sup +/ in its first excited state, /sup 3/P/sub u/, with molecular deuterium was studied over a projectile energy range of 1 to 40 eV in the laboratory system. The product states as determined from the limiting values of the translational exoergicity were BD/sup +/ (/sup 2/..sigma../sup +/) and BD/sup +/ (/sup 2/Pi). The experimental velocity contour maps indicated that BD/sup +/(/sup 2/..sigma../sup +/) was arising through complex formation whereas BD/sup +/ (/sup 2/Pi) was proceeding by a direct mechanism.
Databáze:	OpenAIRE
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