Synthesis of nanosize Co-Rh systems and study of their properties

Autor:	P. V. Sytnikov, S. D. Badmaev, Ekaterina Churakova, N. V. Kurat’eva, A. I. Gubanov, S. V. Korneev, E. Yu. Filatov, V. A. Sobyanin, Pavel E. Plyusnin
Rok vydání:	2011
Předmět:	Thermogravimetric analysis Hydrogen General Chemical Engineering Thermal decomposition Analytical chemistry chemistry.chemical_element Infrared spectroscopy General Chemistry Catalysis chemistry Phase (matter) Physical chemistry Helium Solid solution
Zdroj:	Russian Journal of Applied Chemistry. 84:1677-1683
ISSN:	1608-3296 1070-4272
Popis:	Precursor compounds [Co(NH3)6][Rh(NO2)6] and [Co(NH3)6][Co(NO2)6], solid solutions [Co(NH3)6] [Rh(NO2)6]1−x[Co(NO2)6]x, and solid solutions Na3[Rh1−xCox(NO2)6] were synthesized and studied by IR spectroscopy and elemental, X-ray phase, X-ray diffraction, and thermogravimetric analyses. X-ray phase analysis was employed to examine products of thermal decomposition of precursors in the atmospheres of hydrogen and helium. Catalysts with a Co-Rh active system, supported by ZrO2, were prepared and tested in the reaction of steam conversion of ethanol.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c5c25d66f6299db34d621fd75a19d095 https://doi.org/10.1134/s1070427211100016 Zobrazit plný text záznamu Full text from SpringerLink