Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with Boron Cluster Anions [M(solv)6][BnHn] (M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12)

Autor:	Elena A. Malinina, Lyudmila V. Goeva, Varvara V. Avdeeva, Nikolay T. Kuznetsov, A. S. Kubasov, Svetlana E. Korolenko
Rok vydání:	2020
Předmět:	chemistry.chemical_classification Cadmium Absorption spectroscopy Chemistry Materials Science (miscellaneous) chemistry.chemical_element Infrared spectroscopy Zinc Coordination complex Inorganic Chemistry Crystallography Cluster (physics) Physical and Theoretical Chemistry Boron
Zdroj:	Russian Journal of Inorganic Chemistry. 65:846-853
ISSN:	1531-8613 0036-0236
Popis:	Complex compounds [M(solv)6][BnHn], where M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12, have been synthesized and studied by physicochemical methods (IR spectroscopy, electronic absorption spectroscopy, and X-ray diffraction). The structures of complexes [Cd(DMF)6][B10H10] and [Zn(DMSO)6][B10H10] have been determined by X-ray diffraction. Based on the obtained data, methods for the synthesis of Zn(II) and Cd(II) coordination compounds with nitrogen-containing organic ligands in the presence of boron cluster anions [BnHn]2– (n = 10, 12) have been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c5ba7ba3a24eee1736ad632dc3110365 https://doi.org/10.1134/s0036023620060091 Zobrazit plný text záznamu Full text from SpringerLink