ChemInform Abstract: Phosphorus-Containing 1,3-Zwitterions Formed in the Reaction of Tributylphosphine with 3-Aryl-2-cyanoacrylates

Autor:	N. G. Senchenya, Yu. G. Gololobov, N. V. Slepchenkov, Pavel V. Petrovskii, Victor N. Khrustalev, Alexander S. Peregudov, I. A. Garbuzova
Rok vydání:	2011
Předmět:	Solvent chemistry.chemical_compound chemistry Aryl Polymer chemistry Substituent Tributylphosphine Chemical stability General Medicine Acetonitrile Cyanoacrylates Adduct
Zdroj:	ChemInform. 42
ISSN:	0931-7597
DOI:	10.1002/chin.201108184
Popis:	Tributylphosphine reacts with 3-aryl-2-cyanoacrylates in acetonitrile to afford adducts, viz., phosphorus-containing betaines, thermodynamic stability of which depends on both the nature of the solvent and electronic and spatial characteristics of the aryl substituent in 3-aryl-2-cyanoacrylates.
Databáze:	OpenAIRE
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