Investigation of phase separation mechanisms of thermoset polymer blends by time-resolved SAXS
| Autor: | Christophe Sinturel, Marylène Vayer, Nicolas Boyard, Sönke Seifert, R. Erre |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Molar mass Materials science Polymers and Plastics Scattering Small-angle X-ray scattering Spinodal decomposition Organic Chemistry General Physics and Astronomy Thermosetting polymer Polymer Polyester chemistry Chemical engineering Polymer chemistry Materials Chemistry Small-angle scattering |
| Zdroj: | European Polymer Journal. 41:1333-1341 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/j.eurpolymj.2005.01.005 |
| Popis: | Phase separation induced by crosslinking was studied by time-resolved small angle X-ray scattering in thermoset blend based on unsaturated polyester, styrene and low molar weight saturated polyester as low profile additive. The scattering intensities were analyzed using the Cahn–Hilliard–Cook theory. Combining DSC and DMA experiments allowed us to conclude that phase separation proceeded via spinodal decomposition frozen in the early stage. Apparent diffusion coefficients Dapp were estimated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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