SYNTHESIS AND CHARACTERIZATION OF CADMIUM COMPLEXES WITH PHOSPHORYLATED LIGANDS

Autor:	Judith Felcman, Claudio A. Téllez Soto, Damiana C. N. Lopes, Renata A. Cattapan
Rok vydání:	2001
Předmět:	Cadmium Thermogravimetric analysis Inorganic chemistry chemistry.chemical_element Medicinal chemistry Oxygen Sulfur Phosphocreatine Inorganic Chemistry chemistry.chemical_compound symbols.namesake chemistry symbols Phosphorylation Physical and Theoretical Chemistry Guanidine Raman spectroscopy
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 31:507-516
ISSN:	1532-2440 0094-5714
DOI:	10.1081/sim-100002236
Popis:	Complexes of cadmium(II) with phosphorylated ligands were studied in the solid state. One of these ligands is phosphocreatine (HPCR), an important natural compound and the others are diisopropylphosphorylguanidine (DPG) and diisopropylphosphorylthiourea (DPT). The complexes were synthesized and characterized by elemental and thermogravimetric analyses and IR and Raman spectroscopy. The formed complexes are: [Cd(PCr)Cl]2, Cd(DPG)Cl2 and [Cd(DPT)3Cl]Cl. In the HPCR and DPG complexes, Cd(II) is bound through the oxygen of the phosphoryl group and the nitrogen of the guanidine group and in the DPT complexes through the sulfur atom.
Databáze:	OpenAIRE
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