Reactions of ferrocenyl chalcones with hydrazines and active methylene compounds

Autor:	Marwa El-Hussieny, Hisham Abdallah A. Yosef, Nabila M. Ibrahim, Mohamed R. Mahran
Rok vydání:	2016
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Organic Chemistry Organic chemistry Methylene 010402 general chemistry 01 natural sciences 0104 chemical sciences
Zdroj:	Heterocyclic Communications. 22:69-77
ISSN:	2191-0197 0793-0283
DOI:	10.1515/hc-2016-0006
Popis:	Claisen-Schmidt condensation of ferrocenecarboxaldehyde (2b) with 2-acetylfuran (4) yielded (E)-3-ferrocenyl-1-(2-furyl)prop-2-en-1-one (E -5) together with 1,5-di(2-furyl)-3-ferrocenylpentane-1,5-dione (6). Reactions of the ferrocenyl chalcones 3a,b and 5 with hydrazine hydrate, phenyl hydrazine, ethyl acetoacetate, ethyl cyanoacetate and malononitrile, were also studied. Possible reaction mechanisms were discussed and structures of the new products were unambiguously characterized by common analytical and spectroscopic methods.
Databáze:	OpenAIRE
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