Bandgap tunable Zn3-3Mg3N2 alloy for earth-abundant solar absorber

Autor: Naoomi Yamada, Xiang Cao, Peng Wu, Thomas Tiedje
Rok vydání: 2019
Předmět:
Zdroj: Materials Letters. 236:649-652
ISSN: 0167-577X
Popis: Zn3-3xMg3xN2 alloy layers with x ≤ 0.3 can be epitaxially grown at a temperature as low as 140 °C. The bandgap (Eg) of Zn3-3xMg3xN2 widens from 1.2 to 2.5 eV with increasing x. The Eg value of 1.4 eV is obtained at x = 0.18, and the x = 0.18 film has a large absorption coefficient (104–105 cm−1) in the visible region. The Zn3-3xMg3xN2 with Eg = 1.4 eV shows n-type conductivity with a reasonably high electron mobility of 47 cm2 V−1 s−1. Therefore, Zn3-3xMg3xN2 is a candidate for an earth-abundant solar absorber that can be fabricated at low temperatures.
Databáze: OpenAIRE