Autor: | M. N. Goncharova, T. D. Orlova, V. V. Chernikov, T. V. Balashova, V. P. Vasil'ev |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Russian Journal of Coordination Chemistry. 27:377-380 |
ISSN: | 1070-3284 |
DOI: | 10.1023/a:1011379406964 |
Popis: | The complexation constants and the heats of complexation of 15-crown-5 (15C5) and 18-crown-6 (18C6) with sodium and ammonium ions in aqueous solutions at several temperatures were determined using calorimetry methods. Thermodynamic characteristics (ΔH°, ΔG°, ΔS°, and ΔCp°) of the formation of Na(15C5)+, Na(18C6)+, and NH4(18C6)+were calculated. |
Databáze: | OpenAIRE |
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