Autor: M. N. Goncharova, T. D. Orlova, V. V. Chernikov, T. V. Balashova, V. P. Vasil'ev
Rok vydání: 2001
Předmět:
Zdroj: Russian Journal of Coordination Chemistry. 27:377-380
ISSN: 1070-3284
DOI: 10.1023/a:1011379406964
Popis: The complexation constants and the heats of complexation of 15-crown-5 (15C5) and 18-crown-6 (18C6) with sodium and ammonium ions in aqueous solutions at several temperatures were determined using calorimetry methods. Thermodynamic characteristics (ΔH°, ΔG°, ΔS°, and ΔCp°) of the formation of Na(15C5)+, Na(18C6)+, and NH4(18C6)+were calculated.
Databáze: OpenAIRE