Condensed 1,3,5-triazepines—II

Autor: Béla Ágai, Gy. Simig, Gy. Hornyák, József Fetter, Károly Lempert, Gábor Doleschall
Rok vydání: 1976
Předmět:
Zdroj: Tetrahedron. 32:57-64
ISSN: 0040-4020
DOI: 10.1016/0040-4020(76)80021-x
Popis: A method, based on the reaction of 1-(2-aminoaryl)-2-iminoimidazolidines 8 with phosgen, 1,1′-carbonydiimidazole and thiophosgene, carbon disulfide and 1,1′-thiocarbonyldiimidazole, respectively, has been devised for the synthesis of the title compounds. The compounds 8 are rearranged at elevated temperatures into the isomeric 2-amino-1-(2-amino-ethyl) benzimidazoles 11.
Databáze: OpenAIRE