Preparation of Strong Alkali Anion Exchange Fiber and its Application in Nitrate Adsorption

Autor: Hua Ming Xiao, Yu Wang, Zheng Pu Zhang, Rui Zhi Li
Rok vydání: 2012
Předmět:
Zdroj: Advanced Materials Research. :790-796
ISSN: 1662-8985
Popis: Two kinds of new type of strong alkali anion exchange fibers (PP-g-Vam-ETA and PP-g-Vam-DAC) have been prepared non-toxically and easily via the quaternary reaction of PP-g-Vam matrix (a kind of weakly basic anion-exchange fiber, produced by our Lab.) with ETA (2,3-epoxypropyl trimethyl ammonium chloride) and the grafting reaction of PP-g-Vam matrix with DAC (acyrloxyethyl trimethylammonium chloride). The exchange capacities of PP-g-Vam-ETA and PP-g-Vam-DAC are 2.1018mmol/g (dry fiber) and 2.0217mmol/g (dry fiber) resp. Its adsorption and desorption performances for NO3- have been studied. The adsorption isotherm curve has been well described by Langmuir equation. The fibers have selective adsorption property for NO3-. The static adsorption capacity of PP-g-Vam-ETA is 11.24 mg/g (dry fiber at pH=3); and PP-g-Vam-DAC is 9.79 mg/g (dry fiber at pH=4). The static desorption rate of the two fibers are above 97%.
Databáze: OpenAIRE