Mass spectra of some 3-substituted coumarins

Autor: John S. A. Brunskill, Howard Jeffrey, G. Saint-Ruf, Asish De
Rok vydání: 1980
Předmět:
Zdroj: Journal of Heterocyclic Chemistry. 17:81-86
ISSN: 1943-5193
0022-152X
DOI: 10.1002/jhet.5570170117
Popis: The electron impact mass spectrometric fragmentation pathways for some 3-substituted derivatives of coumarin, benzo[f]coumarin, thieno[3,2-f]coumarin, thieno[2,3-h]coumarin and azacoumarin, viz nitriles, carboxamides, thiocarboxamides and esters were investigated. The initial cleavage of the pyrone ring is found to be largely dependent on the stability, under electron impact, of the attached functional group.
Databáze: OpenAIRE