Anionically induced decomposition of ethyl 2-(2,2-dimethylethylperoxymethyl)propenoate by amines: an easy access to amino epoxyesters and amino ester peroxides

Autor:	Bernard Maillard, Marie Degueil-Castaing, Celine Cramay
Rok vydání:	1999
Předmět:	Solvent chemistry.chemical_compound Degree of unsaturation Primary (chemistry) chemistry Zwitterion Organic chemistry Amine gas treating Peroxide Decomposition Derivative (chemistry)
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :3573-3577
ISSN:	1364-5463 0300-922X
DOI:	10.1039/a907655g
Popis:	Treatment of ethyl 2-(2,2-dimethylethylperoxymethyl)propenoate with primary and secondary amines led to amino epoxides and/or amino peroxides. These compounds were produced by the addition of the amine to the unsaturation of the peroxide to form a zwitterion, followed, respectively, by a proton transfer and an SNi reaction. The formation of one or the other amino derivative was favoured by different reaction conditions (mode of addition of the reactant, solvent). Easy separation of these compounds was possible by chromatography on silica when the reaction was unselective.
Databáze:	OpenAIRE
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