Template-directed intramolecular C-glycosidation. Formation of tetrahydrofurans and application to the synthesis of a higher-order sugar

Autor:	Mark W. Pennington, Peter Warner, Donald Craig
Rok vydání:	1999
Předmět:	chemistry.chemical_compound chemistry Bicyclic molecule Silylation Stereochemistry Intramolecular force Organic Chemistry Drug Discovery Substrate (chemistry) Total synthesis Sugar Biochemistry Enol
Zdroj:	Tetrahedron. 55:13495-13512
ISSN:	0040-4020
Popis:	Cation-mediated cyclisation reactions of silyl enol ether-containing thioglycosides give bicyclic ketotetrahydrofurans. Cyclisation of an analogous 3-phenyl-2-propenyl ether-containing substrate gives an intermediate in the total synthesis of the higher-order sugar 2,3-dideoxy- d - manno -2-octulopyranosonic acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4ec6fd9b805d115b678febf007232ea https://doi.org/10.1016/s0040-4020(99)00834-0 Zobrazit plný text záznamu Full Text from ScienceDirect