Autor:	Mikhail E. Gurskii, D. G. Pershin, K. A. Lyssenko, Vladimir Ponomarev, M. Yu. Antipin, Yu. N. Bubnov
Rok vydání:	2002
Předmět:	chemistry.chemical_compound chemistry Intramolecular force Pyridine Trimethylamine Halogenation Sequence (biology) General Chemistry Crystal structure Medicinal chemistry Tetrahydrofuran Adduct
Zdroj:	Russian Chemical Bulletin. 51:1562-1567
ISSN:	1066-5285
DOI:	10.1023/a:1020991729668
Popis:	Complexes of 2-phenyl-1-boraadamantane with trimethylamine and pyridine were studied by X-ray diffraction analysis. The 2-phenyl-1-boraadamantane adduct with tetrahydrofuran (1) was transformed to 1-hydroxy-2-phenyladamantane via a carbonylation—oxidation sequence. The intramolecular version of the organoborane reaction with organic azides was employed as a key step in the transformation of 2-phenyl-1-boraadamantane adduct (1) into 2-phenyl-1-azaadamantane (5).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4e602e5dc2701560a5b0f7100a1668f https://doi.org/10.1023/a:1020991729668 Zobrazit plný text záznamu Full text from SpringerLink