Investigation of insertion reaction of 10-undecen-1-ol protected with alkylaluminum in En(Ind)2ZrCl2/MAO catalyst system

Autor:	Hideyuki Kaneko, Nobuo Kawahara, Tomoaki Matsugi, Norio Kashiwa, Shinichi Kojoh, Shingo Matsuo
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Olefin fiber Undecanol Process Chemistry and Technology Post-metallocene catalyst Catalysis Active center chemistry.chemical_compound chemistry Insertion reaction Polymer chemistry Physical and Theoretical Chemistry Metallocene Alkyl
Zdroj:	Journal of Molecular Catalysis A: Chemical. 241:156-161
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2005.07.010
Popis:	In this study, insertion reaction of 10-undecen-1-ol (Un-OH) into the metallocene active center was investigated in the absence of olefin monomers. 10-Undecen-1-ol protected with trialkylaluminum (Un-O-AlR 2 ; R = Me, Et, n -Bu, i -Bu) was treated with an En(Ind) 2 ZrCl 2 /MAO catalyst system. The reactant, after quenched with HCl, was analyzed to identify the resulting alcohol compounds by gas chromatography with the comparison of authentic samples and NMR methods. As a result, undecanol (saturated Un-OH) and other alcohol compounds, in which alkyl groups derived from trialkylaluminum were incorporated into Un-OH, were found mainly in the resulting compounds, supporting that Un-O-AlR 2 was inserted into the metallocene active center in the absence of olefin monomers. The mechanism of the insertion reaction of Un-O-AlR 2 was also discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c4bfb8447bec809a3a0bb9abfae88526 https://doi.org/10.1016/j.molcata.2005.07.010 Zobrazit plný text záznamu Full Text from ScienceDirect